Kevin Rose ( Partner at Google Ventures, Founder of Digg, Revision3) has amazing video series called Foundation. Its been around for few years now and features high profile technology leaders like Elon Musk, Kevin Systorm and many others.
My favourite is his interview with Chris Saaca. Chris is one smart cookie.
I really enjoy hearing the personal stories of where people came from. It helps gives me context to what and why they are working on the things they are today.